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(a) Illustrate the thermally allowed product of a [1,3]-(Answered)

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(a) Illustrate the thermally allowed product of a [1,3] sigmatropic rearrangement of the structure portrayed here. Ofcourse, the stereochemical outcome is of critical importance. (b) Choose, from the list that follows,each of the descriptors that apply. The terms are: inversion, retention, suprafacial, antarafacial. (c)Draw a cyclic array to represent a transition structure for the transformation, one that is consistent withyour choice of terms in part ?b?, and (d) specify whether it corresponds to a M?bius or a H?ckel array,and how you can tell whether it?s one of the other..

 

Paper#9255540 | Written in 27-Jul-2016

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